Radical-driven dissociation of odd-electron peptide radical ions produced in 157 nm photodissociation
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چکیده
منابع مشابه
Radical-driven dissociation of odd-electron peptide radical ions produced in 157 nm photodissociation.
Odd-electron a + 1 radical ions generated in the 157 nm photodissociation of peptide ions were investigated in an ion trap mass spectrometer. To localize the radical, peptide backbone amide hydrogens were replaced with deuterium. When the resulting radical ions underwent hydrogen elimination, no H/D scrambling was obvious, suggesting that without collisional activation, the radical resides on t...
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y- and b-type fragment ions produced in the collisional dissociation of arginine-terminated peptide ions are photodissociated with 157-nm light in a linear trap. y-type ions are shown to have the same structure as that of intact peptides of the same sequence with the ionizing proton located at the most basic residue(s). For generic b-type ions, the ionizing proton is shown to be sequestered at ...
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Twenty singly-charged dipeptide ions with N-terminal arginine were photodissociated using 157 nm light in both a linear ion-trap mass spectrometer and a MALDI-TOF-TOF mass spectrometer. Analogous to previous work on dipeptides containing C-terminal arginine, this set of samples enabled insights into the photofragmentation propensities associated with individual residues. In addition to familiar...
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The photodissociation of jet cooled benzyl radicals, C7H7, at 248 nm has been studied using photofragment translational spectroscopy. Two dissociation channels were observed, H + C7H6 and CH3 + C6H4. The translational energy distribution determined for each channel suggests that both dissociation mechanisms occur via internal conversion to the ground state followed by intramolecular vibrational...
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The photodissociation dynamics of the thiophenoxy radical (C6H5S) have been investigated using fast beam coincidence translational spectroscopy. Thiophenoxy radicals were produced by photodetachment of the thiophenoxide anion followed by photodissociation at 248 nm (5.0 eV), 193 nm (6.4 eV), and 157 nm (7.9 eV). Experimental results indicate two major competing dissociation channels leading to ...
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ژورنال
عنوان ژورنال: Journal of the American Society for Mass Spectrometry
سال: 2009
ISSN: 1044-0305,1879-1123
DOI: 10.1016/j.jasms.2009.03.026